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Within organic semiconductors are highly affected by defects. 5, 6 Optical properties as well as charge transport Of periodic lattices like vacancies, dislocation lines, or stackingįaults. 3 Chemical defects arise from substitutional molecules 4 or physical defects because of the distortion 2 There existsĪ variety of structural defects that cause variations from the ideality. Lattice is also important to understand application-relevant properties 1 However, the deviation from the ideal crystal Is the basis to understand charge transport in these materials. Of electrons in terms of their energies and their apparent momenta The molecules is a defined way to describe molecular packing so thatĮlectronic and phonon band structures can be calculated. The properties of organic semiconductors. Is of fundamental importance to understand Which is caused by the crystallization kinetics. Type within thin films of an asymmetric rodlike conjugated molecule, This work identifies and quantifies a specific crystalline defect To the smectic E state at a temperature of 145 ☌. Temperature-dependent in situ experiments reveal that the defectsĬan be healed by approaching the transition from the crystalline state The molecules are integrated in a reversed way, and these fractionsĪre correlated with cooling rates during the sample preparation procedure. The crystalline phase is disturbed by the statistic integration of Peak-broadening phenomena: the known head-to-head stacking within Specific type of molecular disorder is responsible for the observed Patterns with a statistic variation of the molecules reveal that a
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Unusual peak-broadening effects are found, which cannotīe explained using standard models. The films are investigated using X-ray diffraction Thin films are preparedĪt elevated temperatures by crystallization from melt under controlledĬooling rates, thermal-gradient crystallization, and bar coating atĮlevated temperatures. The molecules versus head-to-tail stacking. In the molecular arrangement between the head-to-head stacking of The asymmetric shape of the molecule causesĪn unusual phase behavior, which is a result of a distinct difference (Ph-BTBT-10) is an organic semiconductor with outstanding performance The molecule 2-decyl-7-phenyl-benzothienobenzothiophene